Bis[4-(2-hydroxybenzylideneamino)benzoato-κO]tetrakis(methanol-κO)manganese(II)
نویسندگان
چکیده
In the title mononuclear complex, [Mn(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Mn(II) atom, lying on an inversion centre, exhibits a distorted octa-hedral geometry, defined by two O atoms from two monodentate ligands and four O atoms from four methanol mol-ecules. The crystal structure involves intra-molecular O-H⋯N and O-H⋯O and inter-molecular O-H⋯O hydrogen bonds.
منابع مشابه
Bis[4-(2-hydroxybenzylideneamino)benzoato-κO 1]tetrakis(methanol-κO)cadmium
In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa-hedral coordination, defined by two carboxyl-ate O atoms from two monodentate anions and by four O atoms from four methanol mol-ecules. The crystal structure comprises intra-molecular O-H⋯O and O-H⋯N, and inter-molecular O-H⋯O hydrogen bonds....
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